Taohua HUANG
,
Shengming ZHOU
,
Hao TENG
,
Hui LIN
,
Jun ZOU
,
Jianhua ZHOU
,
Jun WANG
材料科学技术（英）
γ-LiAlO2 single crystal is a promising substrate for GaN heteroepitaxy. In this paper, we present the growth of large-sized LiAlO2 crystal by modified Czochralski method. The crystal quality was characterized by highresolution X-ray diffraction and chemical etching. The results show that the as-grown crystal has perfect quality with the full width at half maximum (FWHM) of 17.7–22.6 arcsec and etch pits density of (0.3–2.2)×104 cm-2 throughout the crystal boule. The bottom of the crystal boule shows the best quality. The optical transmission spectra from UV to IR exhibits that the crystal is transparent from 0.2 to 5.5 μm and becomes completely absorbing around 6.7 μm wavelength. The optical absorption edge in near UV region is about 191 nm.
关键词:
γ-LiAlO2 crystal
,
提拉法
,
化学腐蚀
,
透过光谱
Jun ZOU
,
Shengming ZHOU
,
Xia ZHANG
,
Fenglian SU
,
Xiaomin LI
,
Jun XU
材料科学技术（英）
ZnO thin films were deposited on the substrates of (100) γ-LiAlO2 at 400, 550 and 700℃ using pulsed laser deposition (PLD) with the fixed oxygen pressure of 20 Pa, respectively. When the substrate temperature is 400℃, the grain size of the film is less than 1~$\mu$m observed by Leitz microscope and measured by X-ray diffraction (XRD). As the substrate temperature increases to 550℃, highly-preferred c-orientation and high-quality ZnO film can be attained. While the substratetemperature rises to 700℃, more defects appears on the surface of film and the ZnO films become polycrystalline again possibly because more Li of the substrate diffused into the ZnO film at high substrate temperature. The photoluminescence (PL) spectra of ZnO films at room temperature show the blue emission peaks centered at 430~nm. We suggest that the blue emission corresponds to the electron transition from the level of interstitial Zn to the valence band. Meanwhile, the films grown on γ-LiAlO2 (LAO) exhibit green emission centered at 540 nm, which seemed to be ascribed to excess zinc and/or oxygen vacancy in the ZnO films caused by diffusion of Li from the substrates into the films during the deposition.
关键词:
γ-LiAlO2
,
null
,
null
,
null
Jun ZOU
,
Shengming ZHOU
材料科学技术（英）
About Φ45 mm LiAlO2 single crystal was grown by Czochralski (Cz) technique. However, the full-width at half-maximum (FWHM) value was high to 116.9 arcsec. After three vapor transport equilibration (VTE) processes, we can obtain high-quality LiAlO2 slice with the FWHM value of 44.2 arcsec. ZnO films were fabricated on as-grown slices and after-VTE ones by pulsed laser deposition (PLD). It was found that ZnO films on the two slices have similar crystallinity, optical transmittance and optical band gap at room temperature. These results not only show that LAO substrate is suitable for ZnO growth, but also prove that the crystal quality of LAO substrate slightly affects the structural and optical properties of ZnO film.
关键词:
Crystal structure
,
null
,
null
,
null
Physical Review B
In order to understand the unusually large value of zero-field splitting D for the axial Fe3+ center in a KTaO3 crystal, Zhou made two assumptions in his recent report [Phys. Rev. B 42, 917 (1990)]. In this Comment we will show that his assumption II is qualitatively reasonable, whereas assumption I is unnecessary and doubtful.
关键词:
electric-field;srcl2
Journal of Physics and Chemistry of Solids
The layered ternary ceramics Ti3SiC2 and Ti3AlC2 are isostructural and can form Ti3Si1-xAlxC2 solid solutions combining the advanced properties of both compounds [H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li, Improving the oxidation resistance of Ti3SiC2 by forming a Ti3Si0.90Al0.1C2 solid solution, Acta Mater. 52 (2004) 3631-3637; E.D. Wu, J.Y. Wang, H.B. Zhang, Y.C. Zhou, K. Sun, Y.J. Xue, Neutron diffraction studies of Ti3Si0.9Al0.1C2 compound, Mater. Lett. 59 (2005) 2715-2719; J.Y. Wang, Y.C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3Si0.75Al0.25C2 solid solution, J. Phys.: Condens. Matter 15 (2003) 5959-5968; Y.C. Zhou, J.X. Chen, J.Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3Al1-xSixC2 solid solutions, Acta. Mater. 54 (2006) 1317-1322]. In the present work, the solid solutions of Ti3Si1-xAlxC2 (x = 0, 0.25, 0.33, 0.5, 0.67, 0.75, 1) are investigated by first-principle calculations based on pseudo-potential plan-wave method within the density functional theory framework. The results show that as Al content increases in the solid solution, all the bonds have weakened to certain extents, which lead to an unstable structure both energetically and geometrically. The calculated results are compared and discussed with the reported data for the Ti3Si1-xAlxC2 solid solutions. (c) 2007 Elsevier Ltd. All rights reserved.
关键词:
ceramics;ab initio calculations;electronic structure;electrical;conductivity;oxidation behavior;mechanical-properties;ti3sic2;temperature;ti3alc2;air;si
ZHOU Jiankun LIU Xianghuai CHEN Youshan WANG Xi ZHENG Zhihong HUANG Wei ZOU Shichang Shanghai Institute of Metallurgy
,
Academia Sinica
,
Shanghai
,
China
金属学报(英文版)
The TiN films were synthesized with an alternate process of depositing titanium from a E-gun evaporation source and 40 keV N~+ bombarding onto the target.It is shown from the composi- tion analysis and structure investigations using RBS,AES,TEM,XPS and X-ray diffraction spectrum that the formed fihns are mainly composed of TiN phase with grain size of 30—40 nm and without preferred orientation,the nitrogen content in the film is much less than that in case without N~+ bombarding,and an intermixed region about 40 nm thick exists between the film and the substrate.The films exhibt high microhardness and low friction. ZHOU Jiankun,Ion Beam Laboratory,Shanghai Institute of Metallurgy,Academia Sinica, Shanghai 200050,China
关键词:
TiN film
,
null
Physical Review B
The assignment of the absorption spectrum of Y3Fe5O12 (YIG) made by Scott et al. [Phys. Rev. B 10, 971 (1974)] is shown to be incorrect and a new one is made by diagonalizing the complete cubic crystal-field matrices for d5 ions, involving spin-orbit interaction, given by Zhou et al. [Phys. Rev. B 44, 7499 (1991)]. The Racah parameters B and C, the crystal-field parameter Dq, and the spin-orbit coupling coefficient zeta are determined (in units of cm-1) as B = 783.3(530), C = 2928(3220), Dq = 1336(1300), zeta = 395 for octahedral Fe3+, and B = 606.1(705), C = 2696(2730), Dq = -1117.3(560), zeta = 335 for tetrahedral Fe3+, where the numerals in parentheses are the values adopted by Scott et al. Furthermore, the cubic zero-field splitting parameter a of Fe3+ in YIG is calculated to be a(oct) = 156 X 10(-4) cm-1 and a(tet) = 58.6 X 10(-4) cm-1. The value for a(oct) differs from the value of 189 X 10(-4) cm-1 found for Fe3+ in Y3Ga5O12:Fe3+. These results support speculations made by Geschwind [Phys. Rev. 121, 363 (1961)].
关键词:
fe3+;mn2+
刘守平
,
周上祺
,
王佳眉
,
任勤
腐蚀科学与防护技术
用金相显微镜、扫描电镜、X射线衍射仪和X射线能谱仪对天然气井油管悬挂器腐蚀失效进行了检测分析，并对天然气井油管悬挂器用35CrMo钢进行了盐雾试验，结果表明，天然气中的水和CO2是引起腐蚀的主要介质，腐蚀产物主要是FeCO3，高速天然气冲刷和钢中的非金属夹杂加剧了腐蚀的速度.
CORROSION FAILURE ANALYSIS OF AN OIL TUBE USED IN NATURAL GAS WELL
LIU Shou-ping,ZHOU Shang-qi,WANG Jia-mei,REN Qin
Chongqing University
A failed oil tube used in natural gas well was examined by optical microscope,scanning electron microscope ,X-ray diffractometer and X-ray spectrometer.Corrosion behavior of 35CrMo steel samples of the oil tube were investigated by means of salt spray tests in the laboratory.The results show that CO2 and H2O are primary factors in the corrosion of oil tube.The corrosion product is FeCO3,non-metallic inclusions in the steel and erosion of natural gas fluid played an important role in accelerating the corrosion.
oil tube;
natural gas well；
35CrMo steel；
failure analysis；
corrosion
关键词:
悬挂器
,
null
,
null
,
null
章春香
,
殷海荣
,
刘立营
,
唐保军
材料导报
采用Zhou W C提出的玻璃形成区研究方法探索了铽硼硅酸盐磁光玻璃形成区域范围,采用魔角核磁共振谱仪(MAS NMR)和示差扫描量热仪(DSC)对玻璃结构和特征温度能进行了表征,研究了Tb2O3和Al2O3对玻璃形成能力和玻璃结构的影响,同时引入玻璃析晶参数β讨论玻璃热稳定性.结果表明:Tb2O3的掺入量受玻璃形成区域的限制,在Tb2O3含量为30%(摩尔分数)时以及Al2O3含量为25%(摩尔分数)时玻璃形成能力较强;铽铝硼硅酸盐玻璃结构中硼氧多面体和铝氧多面体主要以四配位的[BO4]和[AlO4]形式存在,仍存在少量三配位的[BO3]和五配位的[AlO5];Tb2O3含量为30%(摩尔分数)的玻璃β值较大,热稳定性能较好.
关键词:
铝硼硅酸盐玻璃
,
磁光玻璃
,
玻璃成形区
,
氧化铽
,
稀土
